Allylic amination by a DNA-diene-iridium(I) hybrid catalyst.
نویسندگان
چکیده
DNA hybrid catalysis goes organometallic: A DNA strand functionalized with diene ligands forms iridium(I) complexes that can efficiently catalyze an allylic amination in aqueous medium (see scheme). The DNA-based complexes show high stability and activity, and their secondary structure influences the stereoselectivity of the reaction.
منابع مشابه
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عنوان ژورنال:
- Angewandte Chemie
دوره 48 24 شماره
صفحات -
تاریخ انتشار 2009